Küsimused

Material Safety Data Sheet (REFRIGERANT R134a)

Information in this format is provided as a service to our customers and is intended only for their use. Others may use it at their own discretion and risk. It is subject to revision as additional knowledge and experience are gained. Please return to this website for the most current version.

1. PRODUCT AND COMPANY IDENTIFICATION

Material Identification

Corporate MSDS Number: HFC 134a CAS Number: 811-97-2

Product Name HFC 134a

Chemical Formula CH2FCF3

Chemical Name 1,1,1,2-tetrafluoroethane

Product Use refrigerant, foaming agent, propellant, solvent

Company Identification

MANUFACTURER/DISTRIBUTOR: JUHUA /MIPUNG/ MIPUNG

Add: 51, Daedong-ro 428beon-gil, Daeso-myeon, Eumseong-gun, Chungcheongbuk-do, Republic of

Korea

Tel.: +82-43-883-3133 Fax: : +82-43-883-3135

PHONE NUMBERS Product Information: +82-43-883-3133 Transport Emergency: +82-43-883-3133 Medical Emergency: : +82-43-883-3133

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name of the substance: 1,1,1,2-TETRAFLUOROETHANE

General name: HALOGENATED HYDROCARBON

CAS Number: 811-97-2

Einecs Number: 212-377-0

Ingredient Name CAS No. Typical Wt. % 1,1,1,2-

tetrafluoroethane (HFC 134a) 811-97-2 100%

3. HAZARDS IDENTIFICATION

EC Classification

EC Directive 67/548/EEC: Not classified

Regulation (EC) No. 1272/2008 (CLP): Gases under pressure – Liquefied gas

Potential Health Effects

INHALATION: Gross overexposure may cause: Central nervous system depression with

dizziness, confusion, incoordination, drowsiness or unconsciousness.

Irregular heart beat with a strange sensation in the chest, "heart thumping",

apprehension, lightheadedness, feeling of fainting, dizziness, weakness,

sometimes progressing to loss of consciousness and death. Suffocation, if

air is displaced by vapors.

SKIN CONTACT: Immediate effects of overexposure may include: Frostbite, if liquid or

escaping vapor contacts the skin.

EYE CONTACT: "Frostbite-like" effects may occur if the liquid or escaping vapors contact

the eyes.

ADDITIONAL HEALTH EFFECTS: Increased susceptibility to the effects of this material

may be observed in persons with pre-existing disease of the: central

nervous system, cardiovascular system.

Carcinogenicity Information: None of the components present in this material at

concentrations equal to or greater than 0.1% are listed by IARC, NTP,

OSHA or ACGIH as a carcinogen.

4. FIRST AID MEASURES

INHALATION: If high concentrations are inhaled, immediately remove to fresh air. Keep

person calm. If not breathing, give artificial respiration. If breathing

is difficult, give oxygen. Call a physician.

SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least

15 minutes, while removing contaminated clothing and shoes. Call a

physician. Wash contaminated clothing before reuse. Treat for frostbite if

necessary by gently warming affected area.

EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least

15 minutes. Call a physician.

INGESTION: Ingestion is not considered a potential route of exposure.

Notes to Physicians: Because of possible disturbances of cardiac rhythm, catecholamine

drugs, such as epinephrine, should only be used with special caution in

situations of emergency life support.

5. FIRE FIGHTING MEASURES

Flammable Properties

Flash Point: Will not burn

Flammable limits in Air, % by Volume LEL: Not Applicable

UEL: Not Applicable Autoignition: >743 ℃(>1369 F)

Fire and Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may occur. Contact of welding or soldering torch flame with high concentrations of refrigerant can result in visible changes in the size and color of torch flames. This flame effect will only occur in concentrations of product well above the

recommended exposure limit, therefore stop all work and ventilate to disperse refrigerant vapors from the work area before using any open flames.

Potential combustibility: HFC-134a is not flammable at temperatures up to 100 deg C (212 deg F) at atmospheric pressure. However, mixtures of HFC-134a with high concentrations of air at elevated pressure can become combustible at ambient temperature. As the temperature of the mixture is increased, lower pressure but still greater than atmospheric pressurecan create the same effect. therefore, HFC-134a should not be mixed with air under pressure for leak testing or other purposes. In general, HFC-134a should not be used or allowed to exist with high concentrations of air above atmospheric pressure. Experimental data have also been reported which indicate combustibility of HFC-134a in the presence of certain concentrations of chlorine.

Fire and Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may occur. Contact of welding or soldering torch flame with high concentrations of refrigerant can result in visible changes in the size and color of the torch flame. This flame effect will only occur in concentrations of product well above the recommended exposure limit, therefore stop all work and ventilate the area before proceeding. Use forced ventilation to disperse refrigerant vapors from the work area before using any open flames.

Extinguishing Media: Use media appropriate for surrounding material. Fire Fighting Instructions: Cool tank/container with water spray. Self-contained breathing

apparatus (SCBA) may be required if cylinders rupture or release under fire conditions. Water runoff should be contained and neutralized prior to release.

6. ACCIDENTAL RELEASE MEASURES

Safeguards (Personnel)

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections

before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE

EQUIPMENT during clean-up. Ventilate area, especially low or enclosed places where

heavy vapors might collect. Remove open flames. Use self-contained breathing

apparatus (SCBA) if large spill or leak occurs.

7. HANDLING AND STORAGE

Handling(Personnel) Use with sufficient ventilation to keep employee exposure below

recommended limits. Handling (Physical Aspects) HFC-134a should not be mixed with air

for leak testing or used for any other purpose above atmospheric pressure. See

Flammable Properties section. Contact with chlorine or other strong oxidizing agents

should also be avoided. Storage Store in a clean, dry place. Do not heat above

52 ℃(126° F).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Normal ventilation for standard manufacturing procedures is

generally adequate. Local exhaust should be used when large amounts

are released. Mechanical ventilation should be used in low or enclosed

places. Refrigerant concentration monitors may be necessary to etermine

vapor concentrations in work areas prior to use of torches or other open

flames, or if employees are entering enclosed areas.

Personal Protective Equipment Impervious gloves and chemical splash goggles should

be used when handlinliquid. Under normal manufacturing conditions, no

respiratory protection is required when using this product. Self-contained

breathing apparatus (SCBA) is required if a large release occurs.

Exposure Guidelines

Exposure Limits R-134a

PEL (OSHA): None Established

TLV (ACGIH): None Established

AEL (Duran): 1000 ppm, 8 & 12 Hr. TWA

WEEL (AIHA): 1000 ppm, 8 Hr. TWA

AEL is Duran's Acceptable Exposure Limit. Where governmentally imposed occupational

exposure limits, which are lower than, the AEL are in effect, such limits shall take

precedence.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Data

Boiling Point: -26.5 ℃ (-15.7° F) @ 736 mm Hg

Vapor Pressure: 96 psia @ 25 ℃ (77° F)

Vapor Density: 3.6 (Air=1.0) @ 25 ℃ (77° F)

%Volatiles: 100 WT%

Solubility in Water: 0.15 WT% @ 25 ℃ (77° F)@ 14.7 psia

Odor: Ether (slight)

Form: Liquefied Gas

Color: Colorless Liquid

Density: 1.21 g/cm3 @ 25 ℃ (77° F)

Specific Gravity: 1.208 @ 77 F (25 ℃)

Evaporation Rate: (CCL 4 = 1); greater than 1

10. STABILITY AND REACTIVITY

Chemical Stability

Conditions to Avoid: Avoid open flames and high temperatures.

Incompatibility with Other Materials: Incompatible with alkali or alkaline earth metals-

powdered Al,Zn, Be, etc.

Decomposition: Decomposition products are hazardous. This material can be

decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming

hydrofluoric acid and possibly carbonyl fluoride. These materials are toxic and irritating.

Contact should be avoided. Polymerization: Polymerization will not occur.

11. TOXICOLOGICAL INFORMATION

Animal Data: 1,1,1,2-TETRAFLUOROETHANE

EYE: A short duration spray of vapor produced very slight eye irritation.

SKIN: Animal testing indicates this material is a slight skin irritant, but not a skin

sensitizer.

INHALATION: 4 hour, ALC, rat: 567,000 ppm.

Single exposure caused: Cardiac sensitization, a potentially fatal disturbance of heart

rhythm associated with a heightened sensitivity to the action of pinephrine.

Lowest-Observed-Adverse-Effect-Level for cardiac sensitization: 75,000 ppm.

Single exposure caused: Lethargy. Narcosis. Increased respiratory rates.These effects

were temporary.

Single exposure to near lethal doses caused: Pulmonary edema.

Repeated exposure caused: Increased adrenals, liver, spleen weight. Decreased uterine,

prostate weight.

Repeated dosing of higher concentrations caused: the following temporareffects-Tremors.

Incoordination

CARCINOGENIC, DEVELOPMENTAL, REPRODUCTIVE, MUTAGENIC EFFECTS: In a

two-year inhalation study, HFC-134a, at a concentration of 50,000 ppm, produced an increase in late-occurring benign testicular tumors, testicular hyperplasic and testicular weight. The no-effect-level for this study was 10,000 ppm. Animal data show slight fetotoxicity but only at exposure levels producinother toxic effects in the adult animal. Reproductive data on male mice show: No change in reproductive performance. Tests have shown that this material does not cause genetic damage in bacterial or mammalian cell cultures, or in animals. In animal testing, this material has not caused permanent genetic damage in reproductive cells of mammals (has not produced heritable genetic damage).

12. ECOLOGICAL INFORMATION

Ecotoxicological Information

AQUATIC TOXICITY: 48 hour EC50 -Daphnia magna: 980 mg/L. 96

hour LC50 -Rainbow trout: 450 mg/L.

13. DISPOSAL CONSIDERATIONS

Waste Disposal

Contaminated HFC-134a can be recovered by distillation or removed to a permitted waste

disposal facility. Comply with Federal, State, and local regulations.

14. TRANSPORTATION INFORMATION

Shipping Information DOT/IMO Receptacles, small, containing gas Hazard Class: 2.2 UN No.: 2037

15. REGULATORY INFORMATION

U.S. Federal Regulations TSCA Inventory Status: Reported/Included. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312

Acute: Yes Chronic: Yes Fire: No Pressure: Yes Reactivity: No HAZARDOUS CHEMICAL LISTS SARA Extremely Hazardous Substance: No CERCLA Hazardous Substance: No SARA Toxic Chemical: No

16. OTHER INFORMATION

NFPA, NPCA-HMIS

NPCA-HMIS Rating

Health: 1 Flammability: 0 Reactivity: 1 Personal Protection rating

to be supplied by user depending on use conditions.

Additional Information

MEDICAL USE CAUTION: Do not use in medical applications involving permanent

implantation in the human body.

The data in this Material Safety Data Sheet relates only to the specific material designated

herein and does not relate to use in combination with any other material or in any process.

Number of revisions

date of final revision 2021-12-22

1

Date of initial creation 2020-04-14

End of MSDS

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

MSDS

TIN PLATE

SHINHWA DYNAMICS Co.,Ltd.

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

1.Information about chemical products and company

A. Product Tin plate

B. Recommended use and usage restrictions

Recommended use

Usage restrictions

For food, miscellaneous, and other containers

No data

C. Supplier

Company

Address

MSDS Writer

Homepage

Date of last revision date

SHINHWA SILUP CO., LTD.

31, Beonnyeong 2-ro, Danwon-gu, Ansan-si, Gyeonggi-do, Republic of

Korea

Quality control department

http://shinhwatp.co.kr

Feb.17th 2022

2.Warning signs including precautionary measures statements

Picture

Sign

Hazardous statements

Precautionary measures

Prevention

Response

Storage

Disposal

Warning

H335 It may cause respiratory system irritation.

H250 When exposed to air, it ignites itself.

P210 Keep away from heat, spark, flame, and high heat.

P222 Keep out of contact with the air.

P261 Avoid inhalation of dust, fume, gas, mist, steam, spray.

P271 Only handle outdoors or in well ventilated areas.

P280 Wear protective gloves, clothing, safety glasses, etc.

P304+P340 Move to fresh air when inhaled and rest in a breathable

position.

P312 If you feel uncomfortable, see a doctor to check.

P335+P334 Shake off any substances on the skin, soak in cold water

or cover with a wet bandage.

P403+P233 Store containers tightly sealed in a well-ventilated

place.

P405 Store in a locked storage area

P501 Dispose of containers in accordance with the relevant

regulations.

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

Other hazards and risks (NFPA) not included in the hazard and risk classification criteria

Tin (Sn)

Iron (Fe)

Sanitation: 0 Fire : No data Reactivity: 0

Sanitation: 2 Fire : No data Reactivity: No data

3.Name and content of components

In manufacturing, small amounts of silicon (0.03% max), manganese (0.5% max),※

aluminum (0.07% max), nickel (0.01% max), copper (0.03% max), molyboden 0.01% max), and

vanadium (0.05% max) may be added.

※ This product is a solidified finished product, and MSDS is not exposed to

chemicals contained in the product.

May be partially exposed in melting conditions, such as items excluded from

preparation, cutting, or welding

Material CAS No. Content

Tin 7440-31-5 2.0 ~ 22.4g/m 2

Iron 7439-89-6 Balance

4.First aid tips

A. When there's a substance in

your eye

B. When it comes into contact

with the skin,

C. When inhaled

D.When you eat

Get emergency medical attention.

Wash skin and eyes immediately in running water for at least 20

minutes upon contact with the substance.

Prevent the spread of contamination in the event of minor skin

contact.

If you feel uncomfortable, see a doctor.

Remove contaminated clothes and shoes and isolate contaminated

areas.

If you are exposed to excessive amounts of dust or fume, remove it

with clean air and take medical measures if you have cough or other

symptoms.

Keep warm and steady.

Move to fresh air

If you do not breathe, perform artificial respiration.

Ensure that medical personnel are aware of the substance and take

protective measures.

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

5. Handling method in case of explosion or fire

A. Proper (inappropriate) fire

control

B. Specific hazards arising

from chemicals

C. Protective equipment and

preventive measures to be worn

during fire fighting

CO2(inappropriate)

Big fire (appropriate) :Dry sand. Drying chemical, Limestone, soda

ash * Water (inappropriate)

Small fire (appropriate) : Dry sand. Drying chemical, Limestone,

soda ash *Foam (inappropriate)

Container may explode when heated

Leakage is at risk of fire/explosion

Inhalation of decomposition products may result in serious injury or

death

Can be re-ignited after digestion

May ignite in contact with moisture

flammable/combustible substances

Some substances can burn quickly with flashes

Some may explode in the event of fire or heating

Serious burns to the skin and eyes when in contact

May produce irritating, corrosive and toxic gases in the event of

fire

It may be molten and transported, so be careful.

Keep water out of the container.

If not dangerous, move the container from the fire area.

Keep safe distance away from the area and digest.

In the event of a tank fire, use unmanned fire extinguishing

equipment in the event of a large fire, and if not possible, let it

burn.

Cool the container with plenty of water even after extinguishing the

fire in the tank.

If there is a high tone or discoloration of the tank during a tank

fire, withdraw immediately.

In case of tank fire, extinguish at maximum distance or use unmanned

fire extinguishing equipment.

In the event of a tank fire, get out of the tank in flames.

6.How to deal with leakage accidents

A. Actions and protective gear

necessary to protect the human

body

Avoid inhalation of (dust, fume, gas, mist, steam, spray).

Do not touch or walk around the exposure.

Remove all ignition sources.

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

B.Action required to protect

the environment

C.Purifying or removing methods

Stop the leak if it's not dangerous.

Pay attention to substances and conditions to avoid.

Wear protective steam protection clothing in case of leakage without

fire.

Leakage may cause contamination

Prevent inflow into waterways, sewers, basement, and confined

spaces.

Cover with dry sand/soil, other non-flammable substances and cover

with plastic sheets to prevent spread and rain.

Using a clean explosion proof tool, collect the leak and place it in

a loosely covered plastic container.

7.Handling and storage method

A.Safety Handling Guidelines

B.Safe Storage Method

Avoid inhalation of (dust, fume, gas, mist, steam, spray).

Refer to engineering management and personal protective equipment.

Only handle outdoors or in well ventilated areas.

Use carefully for handling/storage.

Pay attention to substances and conditions to avoid.

Store tightly sealed in a well ventilated area.

8.Exposure protection and personal protection

A.Exposure standards, biological exposure standards, etc. of chemicals

Domestic regulations

ACGIH regulations

Organic Compounds Biological

Exposure Standards and others

B.Proper engineering management

C. Personal protective gear

Respiratory protection

TWA-2mg/m 3 TIN (Metal)

TWA-0.1mg/m3 TIN (organic compounds)

TWA-2mg/m 3 Iron

TWA-2mg/m 3 TIN

TWA-2mg/m3 TIN

TWA-0.1mg/m 3 TIN

No data

No data

If dust, fume, or mist is generated during operation, ventilate air

pollution so that it is maintained below the exposure standard.

Annotation (metal)

Annotation (Organic Compounds)

Wear respiratory protective gear that is certified by the Korea

Occupational Safety and Health Agency to match the physical chemical

properties of the exposed particulate matter.

If the exposure concentration is less than 1 mg/m3, wear a suitable

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

Eye protection

Hand Protection

physical protection

Type of protective material

type of filter.

If the exposure concentration is lower than 2.5 mg/m3, wear a

loose-fitting hood/helmet type electric respirator or continuous

flow dust mask with the appropriate type of filter.

If the exposure concentration is less than 5 mg/m3, wear a

front-facing or electrically powered half-type or air-supplied

continuous flow/pressure demand half-type respirator with

appropriate filters.

If the exposure concentration is less than 100 mg/m3, wear a

front-facing or helmet/hood type or pressure-required transmission

mask with a suitable filter.

Wear self-air supply (SCBA) or pressure-demand self-air supply

(SCBA) respirators with appropriate filters if the exposure

concentration is lower than 1000 mg/m3.

Wear breathable goggles to protect the eyes against particulate

matter that may cause irritation or other health problems.

Install emergency cleaning facilities (shower type) and face washing

facilities in a location where workers can easily access them.

Wear appropriate protective gloves considering the physical and

chemical properties of the chemical.

Wear appropriate chemical resistant gloves.

Wear heat-resistant gloves when working on high heat.

Wear appropriate protective gloves considering the physical and

chemical properties of the chemical.

Wear proper chemical resistant protective clothing.

Wear heat-resistant clothing when working with high heat.

9.Physical Chemical Properties

TIN

Iron

Physical Status

Colors and Smells

Vapor pressure

Vapor density

Weight (Water=1)

Solid (liquid 232 )℃

White(gloss), odorless

No data

Not Applicable

7.2

Water solubility

Boiling point

Evaporation rate

melting point

Hydrogenion index (pH)

insoluble

Not Applicable

Not Applicable

2260℃

Not Applicable

Physical Status

Colors and Smells

Solid (liquid 1535 )℃

White or gray,

Water solubility

Boiling point

insoluble

Not Applicable

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

Vapor pressure

Vapor density

Weight (Water=1)

odorless

1mmHg(at 1787 )℃

Not Applicable

7.85

Evaporation rate

melting point

Hydrogen ion index

(pH)

Not Applicable

2750℃

Not Applicable

10.Safety and responsiveness

A. Chemical stability and

harmfulness the likelihood of a

reaction

B.conditions to be avoided

C.substance to be avoided

D.Hazardous substances

produced during decomposition

Leakage could be a risk of fire/explosion

Some can be burned but not easily ignited

Non-flammable, the substance itself does not burn, but it can

decompose when heated and cause corrosive/toxic fume

May produce irritating, corrosive and toxic gases in the event of fire

Serious burns to the skin and eyes when in contact

Inhalation of decomposition products can cause serious injury or

death.

Some may break down explosively in the event of fire or

be able to re-ignite after extinguishing a fire

ignite upon contact with moisture

inflammable combustible material

Some substances can flash and ride quickly.

Some react violently with water.

Sources of heat, spark, flame, etc.

dampness

combustible material

hot water

corrosive toxic fume

irritating, corrosive, toxic gases

11.Information on toxicity

A.Information on possible

exposure pathways

B.Health Hazard Information

acute toxicity

oral

transdermal skin

Inhalation

Substances that may have systemic effects on mucous membranes,

eyes and skin(ACGIH, Ministry of Employment Notice

No.2018-24;skin)

LD50 2000mg/kg Rat (OECD TG 423, GLP)- Tin〉

LD50 98600mg/kg Rat (OECD TG 401 GLP)-Iron〉

LD50 2000mg/kg Rat (OECD TG 423, GLP)-Tin〉

LD50 20000mg/kg Guinea pig-Iron〉

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

skin corrosive or irritating

severe eye damage or

irritation

respiratory sensitivity

Skin irritability

carcinogenic

Industrial Safety and

Health Act

Ministry of Employment and

Labor Notice

IARC

OSHA

ACGIH

NTP

EU CLP

germ cell mutagenicity

reproductive toxicity

specific target long-term

toxicity (one exposure)

specific target long-term

toxicity (repeated exposure)

Dust LD50 4.75mg/〉 ℓ 4 Hr Rat (OECD TG 403, GLP)-Tin

Dust LC50>100mg36HrRat (Not applicable to classification due to

lack of reliability of data such as mausoleum, hamster, guinea pig,

etc.)

As a result of skin corrosiveness irritation test using rabbits, the

irritation index is zero, so no irritation OECD TG 404.GLP

No irritation as a result of eye injury irritation test using rabbits, no

significant irritation effects were observed OECD TG 405.GLP

No data

Human, guinea pig, rat and mouse data review results on skin

hypersensitivity, no hypersensitivity-Tin

Skin hypersensitivity test results on guinea pigs show that all iron

oxide substances are not hypersensitive Similar substances:

1309-37-1, 1317-61-9, 1310-14-1

No data

No data

No data

No data

A4(Tin and organic compounds, as Sn)

No data

No data

Genetic mutation test results using mammalian cultured cells in test

tubes negative regardless of presence or absence of metabolic

active systemOECD TG 476, GLP-Tin

Chromosome abnormality test results using mammalian cultured cells

in test tubes, negative regardless of metabolic activity OECD TG 473,

GLP-Tin

Genetic mutations using mammalian cultured cells in the test tube

showed positive for carbony Iron and negative for electrolytic Iron.

OECD TG 476-Iron

Results of oral reproductive toxicity test using rats;,

NOEL 1,000mg/kg/day(OECD TG 421)〉

EHC15 Classified as Category 1 because pneumoconiosis appeared

in workers handling metal tin according to data

caused irritation to the respiratory system

pulmonary injury seen in workers handling metal tin-Tin

Results of repeated oral toxicity test using rats on 28 days, no effect

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

suction hazard

Other Hazardous Effects

is observed even at the highest concentration. NOEL 1,000mg/kg〉

bw/day OECD TG 407.GLP-Tin

Oral Target Organ Systemic Toxicity Test Results in Rats, Liver

Impact - Iron

Results of inhalation targeted organ systemic toxicity test in rats,

NOAEC-5mgm3-iron

No data

No data

12. environmental impact

A. ecotoxic fish

crustaceans

bird

B.Residual and Decomposable

remanency

degradability

C.bioconcentrability

concentrability

biodegradability

D.soil mobility

E.Other adverse effects

LC50 >0.0124mg/ 96 Hr Pimephales promelas(OECD Guidelineℓ

203, GLP)-Tin source:ECHA※

LC50 13.6mg/ 96 Hr (Danio rerio, LC0, 96h, >100,000mg/L,ℓ

analogous substance:51274-00-1, OECD Guideline 203,

Brachydanio rerio, LLO, LC50, 96h, > 10,000mg/L, analogous

substance:1317-61-9-Iron Source:ECHA※

EC50 >100mg/ 48 Hr Daphnia magna(analogous substance CASℓ

No. 1309-37-1 OECD TG 202)-Iron Source:ECHA※

LC50 >0.0192mg/ 72 Hr etc.(Pseudokirchnerella subcapitata,ℓ

OECD TG 201, GLP, No significant effects observed in poorly

soluble substances - Tin Source:ECHA※

No data

No data

No data

No data

(log kd-5.3)-Iron Source:ECHA※

Ceriodaphnia dubia:LOEC-200 /L 7d EPA 1002.0 Source:ECHA㎍ ※

13.Disposal Considerations

A.disposal method

B.Disposal Considerations

Process in one of the following ways

1.solidify

2.Reclamation in a managed landfill facility where designated waste

can be reclaimed.

3.Burn the pulmonary catalyst containing combustible substances

4.Incineration of pulmonary catalysts containing halogen substances

should be carried out at high temperatures.

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

Dispose of the contents in accordance with the relevant laws and

regulations.

14.information required for transportation

A.UN number (UN No.)

B.Proper shipment name

C.Transportation risk rating

D.Container Class

E.Marine Pollutants

1383

Other pyrophoric metals or pyrophoric alloys(PYROPHORIC METAL,

N.O.S. or PYROPHORIC ALLOY, N.O.S)

4.2

Ⅰ

No data

F.Special safety measures that the user needs to know about transportation or means of

transportation

emergency measures in

case of fire

emergency measures in the

event of a spill

F-G

S-M

15.Current state of regulation

A.Regulations under the

Industrial Safety and Health Act

B.Regulations under the

Chemical Substances

Management Act

C.Regulations under the

Hazardous Materials Safety

Management Act

D.Regulations under the Waste

Management Act

E.etc.

domestic regulation

Other domestic regulations

foreign regulation

US Management

Substances subject to working environment measurement

(measurement cycle: 6 months)

controlled hazardous substances

Substances subject to special medical examination (diagnosis cycle:

12 months)

Exposure standard setting substance

Not applicable

Class 2 Metal content 500kg-tin

Class 2 Iron 500kg-CJF

designated waste

No data

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

Information (OSHA Regulations)

US Management

Information(CERCLA regulations)

US Management

I n f o r m a t i o n ( E P C R A

302regulations)

US Management

I n f o r m a t i o n ( E P C R A

304regulations)

US Management

I n f o r m a t i o n ( E P C R A

313regulations)

US Management

Information

(Rotterdam Convention

Substances)

US Management

Information

(Stockholm-contracted

substances)

US Management

Information

(Montreal Protocol

Substances)

EU classification

i n f o r m a t i o n ( c o n f i r m e d

classification results)

EU classification

information(dangerous sign)

EU classification

information(safety sign)

No data

No data

No data

No data

No data

No data

No data

No data

No data

No data

No data

No data

No data

16.Additional References

A.source of data

HSDB(property)

HSDB(smell)

ICSC(melting point)

ICSC (Melt Point)

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

HSDB (solubility)

ICSC (Specific gravity)

ECHA (orally)

ECHA (Transdermal)

ECHA (Inhalation)

ECHA (skin corrosive or irritating)

ECHA (severe eye damage or irritating)

ECHA (Dermatological Sensitivity)

ECHA (Germ Cell Mutagenicity)

ECHA (Reproductive Toxicity)

NITE, IPCS (specific target long-term toxicity (one exposure))

ECHA (specific target long-term toxicity (repeated exposure))

ECHA (fish)

ECHA (crustaceans)

ECHA (birds)

ECHA (Soil Mobility)

ECHA (Other Harmful Effects)

B.Original creation date: April 11, 2015.

C.the number of revisions and the date of the last revision;

Number of revisions: 3

The last revision date is February 17th, 2022.

D.Other

Refer to: Material Safety and Health Materials of Korea Industrial Safety Management Corporation

Although this data has been prepared for the purpose of communicating information to users in

accordance with known knowledge and the Industrial Safety and Health Act, it cannot be said that

all hazardous substances specified in this data are described. Therefore, the user must carefully

consider the precautions before using this information to ensure compliance with applicable laws

and regulations relating to use and disposal.

Ensure that this document does not guarantee responsibility for the consequences of reference

material and that final compliance assessments are made at the discretion of the user in the use of

the product.

This document is written according to the standard used, so it is recommended that the person

handling it should develop a suitable safety measure for special handling.

Tin plate MSDS SHINHWA DYNAMICS CO., LTD.

This document is intended for informational purposes and should not be understood as

guaranteeing the characteristics and quality of the product.

- This data was prepared in accordance with Article 41 of the Industrial Safety and Sanitation Act.-

Copyrightⓒ 2022 KG Steel All Right Reserved

Material Safety Data Sheet [This sheet was made by Industrial Safety and Health Act, Article 41, in Korea]

Electrolytic Tin Plate(TP)

Document No. MSDS-40 Revision Ver. 5

Writing Department

QM Revition date 2022.04.04

Copyrightⓒ 2022 KG Steel All Right Reserved

1. Chemical Product and Company Identification

A. Product Name : Electrolytic Tin Plate

B. Recommended Use of Product and restrictions on use

Recommended Use of Product : Cans, officesupplies, etc..

restrictions on use : None

C. Manufacturer / Supplier / Distributor Information

Name: KG Steel

Address : 1228, Bukbusaneom-ro, Songak-Eup, Dangjin-Si, Chungnam province,

343-823, Korea

Emergency phone number : +82-41-351-8527 / +82-41-351-8115

2. Hazards Identification

A. Hazard․Risk Classification : N/A

B. Label elements including precautionary statements

Symbol : N/A

Signal Word : N/A

Hazard-Risk Statement : N/A

Precautionary Statement

Prevention : N/A

Response : N/A

Storage : N/A

Disuse : N/A

C. Other Hazard․Risk which are not included in the classification criteria

TIn

Health : 1 Fire : N/A Reaction : N/A

Iron

Health : 2 Fire : N/A Reaction : N/A

1/17

Copyrightⓒ 2022 KG Steel All Right Reserved

3. Composition/Information on ingredients

※ Please refer to the MSDS of iron

※ C, Si, Mn, Al and Ti may be added in minor amounts during manufacturing

※ This product is solid finished product. There is no possibility of exposure to chemicals

contained in the product. It may be partially exposed in the melting state such as

cutting, melting etc.

4. First aid measures

A. Eye contact

Get medical advice/attention

Rinse cautiously with water for several minutes

B. Skin contact

Rinse cautiously with water for several minutes

Remove contaminated clothing and shoes and isolate contaminated areas

Wash clothing and shoes thoroughly before reuse

Get medical advice/attention

C. Inhalation

Get medical advice/attention

Remove person to fresh air

If not breathing, give artificial respiration

If breathing is difficult, give oxygen

D. Ingestion

Do not feed anything to an unconscious person

Get medical advice/attention

E. Doctor’s notes

Have the healthcare worker know about the material and take protective measures

Do not administer adrenaline.

2/17

Name Other name CAS No. Percentage

Tin Stannum 7440-31-5 Max 0.12%

Iron Ferrium 7439-89-6 Max 98.6%

Copyrightⓒ 2022 KG Steel All Right Reserved

5. Fire-Fighting measures

A. Suitable (and unsuitable) extinguishing media

Small fire: dry sand, dry chemical, alcohol-resistant foam, water spray, regular foam,

CO2 (suitable extinguishing media)

Large fires: water spray / mist, regular foam (suitable extinguishing media)

High pressure water (improper extinguishing agent)

B. Specific hazards arising from the chemical

Can be ignited by heat, sparks and flames

Some can burn, but not easily ignite

May cause irritation and toxic gas in case of fire

Inhalation of the substance may be harmful

Some fluids may cause dizziness, vapors that may cause suffocation

C. Special protective equipment and precautions for fire-fighters

Tin

Escape the area and extinguish the fire at a safe distance

Move container from fir area if it is not hazardous

Iron

Move container from fir area if it is not hazardous

If it is impossible to extinguish the fire, protect the surroundings and let the fire

extinguish itself

6. Accidental release measures

A. Personal precautions, protective equipment and emergency procedures

Remove all ignition sources

Stop the leak if it is not dangerous

Note the substances and conditions to avoid

Ventilate the contaminated area

Do not touch or walk with exposed material

Avoid dust formation

Do not enter if you do not need to enter or do not have protective equipment

3/17

Copyrightⓒ 2022 KG Steel All Right Reserved

B. Environmental precautions and protective procedures

Prevent entry into waterways and sewers.

C. Methods and materials for containment and cleaning up

In case of powder leakage, cover with plastic sheet to prevent spread and keep dry

7. Handling and storage

A. Precautions for safe handling

Note the substances and conditons to avoid

Wash thoroughly after handling

Refer to engineering controls and personal protective equipmenet

Be careful of high temperatiures

B. Conditions for safe storage

Keep tightly closed

Store in a cool, dry place

Note the substances and conditions to avoid

8. Exposure controls & personal protection

A. Control parameters

Domestic regulations

TIn: TWA : 2 ㎎/㎥ Tin(Metal)

TWA : 0.1 ㎎/㎥ Tin(Organic compound)

Iron : TWA 1mg/m³`

ACGIH

TIn: TWA 2 mg/m³ Tin (Metal)

TWA 2 mg/m³ Tin (Metal)

TWA 0.1 mg/m³ Tin (Organic compound)

Iron : N/A

Biological exposure standard : N/A

B. Appropriate engineering controls

Use process isolation, local exhaust, or keep air level below exposure standard

4/17

Copyrightⓒ 2022 KG Steel All Right Reserved

C. Personal protective equipment

Respiratory protection

Tin (Metal)

Wear respiratory protection which has been approved by the Korean Occupational

Safety and Health Administration in accordance with physicochemical properties of

the particulate matter to be exposed.

If the exposure level is lower than 20mg/m³, wear a respiratory protective gear of

half mask type that have appropriate type filter.

If the exposure concentration is lower than 50mg/m³, wear a dust mask of loose-

fitting hood /powered helmet type or continuous-flow type that have appropriate

type filter.

If the exposure concentration is lower than 100mg/m³, wear a respiratory protective

gear of full type or powered and half type or Air-fed continuous-flow / pressure-

demanding type that have appropriate type filter.

If the exposure concentration is lower than 2000mg/m³, wear a ventilation mask of

full type or hood/helmet type or Pressure-demanded type that have appropriate

type filter.

If the exposure concentration is lower than 20000mg/m³, wear self-contained

breathing apparatus (SCBA) or self-contained breathing apparatus with pressure-

demand self-contained breathing apparatus (SCBA) with appropriate filter.

Tin (Organic compound)

Wear respiratory protection which has been approved by the Korean Occupational

Safety and Health Administration in accordance with physicochemical properties of

the particulate matter to be exposed.

If the exposure level is lower than 1mg/m³, wear a respiratory protective gear of

half mask type that have appropriate type filter.

If the exposure concentration is lower than 2.5mg/m³, wear a dust mask of loose-

fitting hood /powered helmet type or continuous-flow type that have appropriate

type filter.

If the exposure concentration is lower than 5mg/m³, wear a respiratory protective

gear of full type or powered and half type or Air-fed continuous-flow / pressure-

5/17

Copyrightⓒ 2022 KG Steel All Right Reserved

demanding type that have appropriate type filter.

If the exposure concentration is lower than 100mg/m³, wear a ventilation mask of

full type or hood/helmet type or Pressure-demanded type that have appropriate

type filter.

If the exposure concentration is lower than 1000mg/m³, wear self-contained

breathing apparatus (SCBA) or self-contained breathing apparatus with pressure-

demand self-contained breathing apparatus (SCBA) with appropriate filter.

Iron

Wear respiratory protection which has been approved by the Korean Occupational

Safety and Health Administration in accordance with physicochemical properties of

the particulate matter to be exposed.

If the exposure level is lower than 10mg/m³, wear a respiratory protective gear of

half mask type that have appropriate type filter.

If the exposure concentration is lower than 25mg/m³, wear a dust mask of loose-

fitting hood /powered helmet type or continuous-flow type that have appropriate

type filter.

If the exposure concentration is lower than 50mg/m³, wear a respiratory protective

gear of full type or powered and half type or Air-fed continuous-flow / pressure-

demanding type that have appropriate type filter.

If the exposure concentration is lower than 1000mg/m³, wear a ventilation mask of

full type or hood/helmet type or Pressure-demanded type that have appropriate

type filter.

If the exposure concentration is lower than 10000mg/m³, wear self-contained

breathing apparatus (SCBA) or self-contained breathing apparatus with pressure-

demand self-contained breathing apparatus (SCBA) with appropriate filter.

Eye protection

Use chemical protective eyewear and protective face

Install eyewash station and emergency shower near work area

Hand protection

Wear suitable chemical resistant gloves

6/17

Copyrightⓒ 2022 KG Steel All Right Reserved

Body protection

Wear suitable chemical resistant clothing

9. Physical and chemical properties

TIn

A. Appearance

Appearance : Solid(Powder)

Colour : Gray (Polish)

B. Odour : Odorless

C. Odour threshold : N/A

D. pH : N/A

E. Meting point/freezing point : 231.9 ℃

F. Initial boiling point and boiling range : 2,260 ℃

G. Flash point : N/A

H. Evaporation rate : N/A

I. Flammability(solid, gas) : Flammability (exposure to heat in the form of dust or

spontaneous ignition of chemicals)

J. Upper/lower flammability or explosive limits : N/A

K. Vapour pressure : 1mmHg(at 1787 ℃)

L. Solubility : (Insolubility)

M. Vapor density : N/A

N. Specific gravity : 7.2

O. N-octanol/water Partition coefficient : N/A

P. Auto-ignition temperature : N/A

Q. Decomposition temperature : N/A

R. Viscosity : 1.85 (240 ℃)

S. Molecular weight : 118.71

Iron

A. Appearance

Appearance : Solid

Colour : White or Gray

7/17

Copyrightⓒ 2022 KG Steel All Right Reserved

B. Odour : N/A

C. Odour threshold : N/A

D. pH : N/A

E. Meting point/freezing point : 1535℃

F. Initial boiling point and boiling range: 2750℃

G. Flash point : None

H. Evaporation rate : None

I. Flammability(solid, gas) : None

J. Upper/lower flammability or explosive limits : None

K. Vapour pressure : 1 mmHg (at 1787℃)

L. Solubility : (Water solubility: Insolubility. Solvent availability : availability : acid.

Insolubility : alkali, Alcohol, ether)

M. Vapor density : None

N. Specific gravity : 7.86 ((water=1))

O. N-octanol/water Partition coefficient : None

P. Auto-ignition temperature : None

Q. Decomposition temperature : None

R. Viscosity : None

S. Molecular weight : 55.85

10. Stability and reactivity

A. Chemical stability and possibility of hazardous reactions

TIn

Some can burn, but not easily ignite

Non-flammable materials are not burned but, decompose on heating and may

cause corrosive toxic fumes.

Iron

Can be ignited by friction, heat, spark, flame

May re-ignite after extinguish the fire

Some materials burn with intense heat

8/17

Copyrightⓒ 2022 KG Steel All Right Reserved

Dust and fumes can form explosive mixtures with air

May cause irritating, corrosive and toxic gases in case of fire

Inhalation and contact with vapors, substances, and decomposition products

may result in serious injury or death

Oxides in metal fires have serious health hazards

B. Conditions to avoid

Tin : Heat, spark, flame, etc

Iron : Heat, spark, flame, etc

C. Incompatible materials

Tin : Conbustible material, reducing material

Iron : Water

D. Hazardous decomposition products

Tin : Corrosive/Toxic fume

Irritant, corrosive, toxic gas

Iron : Irritant, corrosive, toxic gas

11. Toxicological information

A. Information on the likely routes of exposure : N/A

Tin : N/A

Body can be absorbed by inhalation.

Can be absorbed by suction and digestice organ

Body can be absorbed by inhalation of vapor.

Can be absorbed by inhalation, skin and digestive system.

Iron : N/A

Body can be absorbed by inhalation.

Can be absorbed by suction and digestice organ

Body can be absorbed by inhalation of vapor.

Can be absorbed by inhalation, skin and digestive system.

9/17

Copyrightⓒ 2022 KG Steel All Right Reserved

B. Health hazards information

Acute toxic

Oral

Tin : LD50 > 2000 mg/kg Rat (OECD TG 423, GLP)

Iron : LD50 98600 mg/kg Rat (OECD TG 401 Male)

Dermal

Tin : LD50 > 2000 mg/kg Rat (OECD TG 402, GLP)

Iron : LC50 20000 mg/kg Guinea pig

Inhalation

Tin : Dust LC50 > 4.75 mg/ℓ 4 hr Rat (OECD TG 403, GLP)

Iron : Dust LC50 > 100mg/m³ 6 hr Rat (Not applicable to classification due to

lack of reliability of data such as mouse, hamster and guinea pig)

Skin corrosive/irritant

Tin : As a result of skin corrosion / irritation test on rabbit, no irritation beacuse

the irritation index is zero OECD TG 404, GLP

Iron : As a result of skin corrosion / irritation test on rabbits, no corrosivity

OECD TG 404

Serious eye damage/eye irritation

Tin : As a result of eye damage / irritation test using rabbit,

no irritation due to no significant irritation effect OECD TG 405, GLP

Iron : As a result of eye damage / irritation test on rabbots, no stimulation

OECD TG 405

Respiratory sensitization : N/A

Skin sensitization

Tin : As a result of reviewing data from humans, guinea pigs, rats and mice,

no skin sensitization.

Iron : As a result of the skin sensitization test for guinea pigs,

all iron oxide materials are non-irritant

Similar materials : 1309-37-1, 1317-61-9, 1310-14-1

10/17

Copyrightⓒ 2022 KG Steel All Right Reserved

Carcinogenicity

Industrial Safety and Health Act : N/A

Ministry of Labor examination : N/A

IARC : N/A

OSHA : N/A

ACGIH

TIn: A4 (Tin and organic compounds, as Sn)

Iron : N/A

NTP : N/A

EU CLP : N/A

Germ cell Mutagenicity

Tin : As a result of gene mutation test using in vitro cultured mammalian cells,

It is negative regardless of metabolic activation system OECD TG 476, GLP

As a result of the chromosome aberration test using the cultured cells of

the mammalian cells in vitro, It is negative regardless of metabolic activation

system.OECD TG 471, GLP

As a result of the mutation test using the in vitro microorganism, It is

negative regardless of metabolic activation system.OECD TG 473, GLP

Iron : As a result of gene mutation test using in vitro cultured mammalian cels,

carbonyl iron is positive and electrolytic iron is negative OECD TG 476

Germ cell toxicity

Tin : As a result of the oral reproductive toxicity test using the rats,

NOEL > 1,000 mg/kg/day

(OECD TG 421)

Iron : N/A

Specific target organ toxicity(Single exposure)

Tin : Because pneumoconiosis occurred in workers handling metal tin, they were

classified as Category 1 according to EHC15 data

Causes respiratory irritation

Iron : N/A

11/17

Copyrightⓒ 2022 KG Steel All Right Reserved

Specific target organ toxicity(Repeated exposure)

Tin : Lung damage is seen in workers handling tin metal

As a result of 28 days oral toxicity test using rats, No effect observed

at maximum concentrationNOEL > 1,000 mg/kg bw/day OECD TG 407, GLP

Iron : As a result of oral target organ systemic toxicity test on rats,

the liver are affected

As a result of inhalation target organ systemic toxicity test or rats,

NOAEC = 5mg/m³

Aspiration hazard : N/A

Other harmful effects : N/A

12. Ministry of Labor examination

A. Ecotoxicity

Fish

Tin : LC50 > 0.0124 mg/ℓ 96 hr Pimephales promelas (OECD Guideline 203, GLP)

Iron : LC50 13.6mg/ℓ 96 hr (Danio rerio, LC0, 96h, >100,000mg/L,

Similar materials :51274-00- 1, OECD Guideline 203,

Brachydanio rerio, LL0, LC50, 96h, > 10,000mg/L,

Similar materials : 1317-61-9

Crustacea

Tin : N/A

Iron : EC50 > 100mg/ℓ 48hr Daphnia magna

(Similar materials CAS No. 1309-37-1 OECD TG 202)

Algae

Tin : EC50 > 0.0192 mg/ℓ 72 hr Others (Pseudokirchnerella subcapitata, OECD TG 201,

GLP, No significant effects were observed with poorly soluble materials.)

Iron : N/A

B. Persistence and degradability

Persistence : N/A

Degradability : N/A

12/17

Copyrightⓒ 2022 KG Steel All Right Reserved

C. Bioaccumulative potential

Accumulation : N/A

Biodegradable : N/A

D. Mobility in soil : N/A

E. Other adverse effects

Tin : Crustacea Ceriodaphnia dubia : LOEC = 200µg/L 7d EPA 1002.0

Iron : N/A

13. Disposal considerations

A. Disposal method

Tin : N/A

Iron : Use one of the following methods.

1. Solidify

2. Land a designated waste in a managed landfill

3. Incinerate spent catalysts containing flammable materials

4. In case of incinerating waste catalyst containing halogenated material, incinerate

at high temperature

B. Disposal precaution

Tin : Dispose of contents container according to applicable regulations

Iron : If specified in the Waste Management Act, consider the precautions specified

in the regulations

14. Transport information

A. UN Number (UN No.)

Tin : N/A

Iron : 3089

B. UN proper shipping name

Tin : N/A

Iron : Metal powder(Flammable)(Except that the name of the product is not specified)

METAL POWDER, FLAMMABLE, N.O.S.

13/17

Copyrightⓒ 2022 KG Steel All Right Reserved

C. Transport hazard

Tin : N/A

Iron : 4.1

D. Packing group

Tin : N/A

Iron : Ⅱ

E. Environmental hazards

Tin : N/A

Iron : Not applicable

F. Special safety measures that the user needs or needs to know about transport

or means of transport.

Emergency measures in case of fire

Tin : N/A

Iron : F-G

Emergency measures in case of leak

Tin : N/A

Iron : S-G

15. Regulatory information

A. Industrial Safety and Health Act

Tin : Toxic substances to be controlled

Working environment Measured material (measurement cycle: 6 months)

Special medical examination subject substance (diagnosis period: 12 months)

Exposure standard setting substance

Iron : Toxic substances to be controlled

Exposure standard setting substance

B. Toxic Chemical Control Act : N/A

C. Dangerous Material Safety Control Act

Tin : Class 2 metal powder 500kg

Iron : Class 2 Iron powder 500kg

14/17

Copyrightⓒ 2022 KG Steel All Right Reserved

D. Wastes Management Act

Tin : N/A

Iron : Designated waste

E. Other requirements in domestic and other countries

Domestic regulation

Residual Organic Pollutant Control Act : N/A

Foreign regulation

US Administration Information(OSHA Rule : N/A

US Administration Information(CERCLA Rule)

US Administration Information (EPCRA 302 Rule) : N/A

US Administration Information (EPCRA 304 Rule) : N/A

US Administration Information (EPCRA 313 Rule)

US Administration Information (Rotterdam Convention material) : N/A

US Administration Information (Stockholm Convention substance) : N/A

US Administration Information (Montreal Protocol substance) : N/A

EU Classification information (Confirmed classification result) : N/A

EU Classification information (Risk phrases) : N/A

EU Classification information (Safety phrases) : N/A

16. Other information

A. Source of material

Tin

HSDB (Appearance)

HSDB (B. Colour)

ICSC (E. Melting point/Freezing point)

ICSC (F. Initial boiling point and boiling range)

HSDB (L. Solubility)

ICSC (N. Specific gravity)

HSDB (R. Viscosity)

pubchem(S. Molecular weight)

15/17

Copyrightⓒ 2022 KG Steel All Right Reserved

ECHA (Oral)

ECHA (Dermal)

ECHA (nhalation)

ECHA (Skin corrosive/irritant)

ECHA (Serious eye damage/eye irritation)

ECHA (Skin sensitization)

ECHA (Germ cell Mutagenicity)

ECHA (Germ cell toxicity)

NITE, IPCS (Specific target organ toxicity(Single exposure))

ECHA (Specific target organ toxicity(Repeated exposure))

ECHA (Fish)

ECHA (Algae)

ECHA (E. Other adverse effects)

Iron

HSDB (Appearance)

HSDB (Colour)

HSDB (E. Melting point/Freezing point)

HSDB (F. Initial boiling point and boiling range)

HSDB (K. Vapour pressure)

ICSC (L. Solubility)

ICSC (N. Specific gravity)

pubchem (S. Molecular weight)

ECHA (Oral)

ECHA (Dermal)

ECHA (Skin corrosion or irritation)

ECHA (Serious eye damage or irritation)

ECHA (Skin sensitization)

ECHA (Germ cell mutagenicity)

(Reproductive toxicity)

NITE, CICAD (Specific target organ toxicity (Repeated exposure))

16/17

Copyrightⓒ 2022 KG Steel All Right Reserved

ECHA (Fish)

ECHA (Crustacean)

ECHA (D. Mobility in soil)

B. Issuing date : 2004.12

C. Revision number : 4 Times

D. Revision number : 2020.04.03

E. Others

This information is based on the industrial Safety and Health Act and the knowledge

and related materials to date. However, the risk of hazardous substances is not written

to all the risks of hazardous substances exist there may be unknown hazards of all

chemicals in this material may be prescribed. Therefore, our customers and potential

customers should review this information and precaution, look precautions carefully

and verify suitability about applicable laws and regulations related to the use and

disposal of this product.

This information is intended solely for the purpose of describing the health, safety and

environmental requirements of the product handler and should not be construed as

an endorsement of the characteristics or quality of the product.

Please understand that it is the sole responsibility of the user to evaluate the final

suitability of the product, as it is impossible to control the actual application of this

product. It is necessary to establish appropriate safety measures in accordance with the

application and usage in case of special handling.

This document can be revised based on the new information.

17/17